Publications
From crossed molecular-beam reaction dynamics and ionization mechanisms, to the analytical applications the group develops independently today.
Independent Research 2019–present
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para-Donor Effects in PyNO Push Ligands Control O–O Bond Cleavage of TPAFe(III)-Acylperoxo to High-Valent Fe(IV)=O or Fe(IV)=O Radical Cation Species Co-corresponding authordoi:10.1021/acs.inorgchem.5c05784
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A thermal perspective on MALDI ionization: A long journey from fundamental mechanisms to a practical solution for carbohydrate analysis Corresponding authorInvited reviewdoi:10.1016/j.ijms.2025.117516
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Exploring Electrochemical C(sp3)–H Oxidation over Fe Complexes: Ligand Effect on the Rate–Bond Dissociation Energy Relationship and Reaction Mechanism doi:10.1021/acscatal.5c01183
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Overcoming the Tradeoff Between Reaction Rate and Overpotential in Dinuclear Cobalt Complex Catalyzed Electrochemical Water Oxidation Co-corresponding authordoi:10.1002/chem.202403583
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Advanced Pd-NAPA Precatalysts for Broad-Scope Kumada–Tamao–Corriu Couplings of Challenging Aryl Chlorides Co-corresponding authordoi:10.1002/ajoc.202500332
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Advancing Carbohydrate Quantification in MALDI Mass Spectrometry by Rapidly Freeze-Drying Droplet (RFDD) Method Corresponding authordoi:10.1039/D3AN02201C
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Manipulating the Rate and Overpotential for Electrochemical Water Oxidation: Mechanistic Insights for Cobalt Catalysts Bearing Noninnocent Bis(benzimidazole)pyrazolide Ligands Co-corresponding authordoi:10.1021/acsorginorgau.3c00061
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New Processes for Ionizing Nonvolatile Compounds in Mass Spectrometry: The Road of Discovery to Current State-of-the-Art doi:10.1021/jasms.3c00122
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High-Resolution Intact Protein Analysis via Phase-Modulated, Stepwise Frequency Scan Ion Trap Mass Spectrometry doi:10.1021/acs.analchem.4c02775
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Dinuclear Cobalt Complexes for Homogeneous Water Oxidation: Tuning Rate and Overpotential through the Non-Innocent Ligand Co-corresponding authordoi:10.1002/cssc.202201317
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Hexamethyldisilazane-Mediated Amidination of Sulfonamides and Amines with Formamides doi:10.1021/acs.joc.2c01902
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Self-assembled lanthanide-based helixes: synthetic control of the helical handedness by chirality of the ligand doi:10.1039/D1DT03833H
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Access to Monomeric Lead(II) Hydrides with Remarkable Thermostability and Their Use in Catalytic Hydroboration of Carbonyl Derivatives doi:10.1021/acs.inorgchem.2c01658
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Reactivity-Tunable Palladium Precatalysts with Favorable Catalytic Properties in Suzuki–Miyaura Cross-Coupling Reactions Co-corresponding authordoi:10.1002/cctc.202200736
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Applications of vacuum MAI on a portable mass spectrometer Corresponding authordoi:10.1016/j.ijms.2022.116798
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Bulky Di(1-adamantyl)phosphinous Acid-Ligated Pd(II) Precatalysts for Suzuki Reactions of Unreactive Aryl Chlorides doi:10.1021/acsomega.1c06430
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Novel ion source for a portable mass spectrometer Corresponding authordoi:10.1002/rcm.8503
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Sublimation Driven Ionization for Use in Mass Spectrometry: Mechanistic Implications doi:10.1021/jasms.0c00297
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New Strategy to Preserve Phosphate by Ionic Liquid Matrices in Matrix-Assisted Laser Desorption/Ionization: A Case of Adenosine Nucleotides Corresponding authordoi:10.3390/molecules25051217
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基質輔助雷射脫附游離法之研究與展望 Corresponding authordoi:10.6623/chem.201906_77(2).006
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Direct sub-atmospheric pressure ionization mass spectrometry: Evaporation/sublimation-driven ionization is amazing, fundamentally, and practically doi:10.1002/jms.5018
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An overview of biological applications and fundamentals of new inlet and vacuum ionization technologies doi:10.1002/rcm.8829
Ionization Techniques in Mass Spectrometry 2009–2018
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Spontaneous Charge Separation and Sublimation Processes Are Ubiquitous in Nature and in Ionization Processes in Mass Spectrometry doi:10.1007/s13361-017-1788-7
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Development of an Easily Adaptable, High Sensitivity Source for Inlet Ionization First authordoi:10.1039/C7AY00995J
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Laser Pulse Width Dependence and Ionization Mechanism of Matrix-Assisted Laser Desorption/Ionization doi:10.1007/s13361-017-1734-8
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Simplifying the Ion Source for Mass Spectrometry First authordoi:10.1002/rcm.7718
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Formation of Metal-Related Ions in Matrix-Assisted Laser Desorption Ionization doi:10.1007/s13361-016-1424-y
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Ionization Mechanism of Matrix-Assisted Laser Desorption/Ionization First authordoi:10.1146/annurev-anchem-071114-040315
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Ion-to-Neutral Ratios and Thermal Proton Transfer in Matrix-Assisted Laser Desorption/Ionization First authordoi:10.1007/s13361-015-1112-3
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Ion Intensity and Thermal Proton Transfer in Ultraviolet Matrix-Assisted Laser Desorption/Ionization First authordoi:10.1021/jp5008076
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Theoretical investigation of low detection sensitivity for underivatized carbohydrates in ESI and MALDI doi:10.1002/jms.3889
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Does decarboxylation make 2,5-dihydroxybenzoic acid special in matrix-assisted laser desorption/ionization? doi:10.1002/rcm.6885
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Fluorescence spectroscopy of UV-MALDI matrices and implications of ionization mechanisms doi:10.1063/1.4898372
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Is energy pooling necessary in ultraviolet matrix-assisted laser desorption/ionization? doi:10.1002/rcm.6765
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Thermal proton transfer reactions in ultraviolet matrix-assisted laser desorption/ionization doi:10.1007/s13361-013-0792-9
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Ion-to-neutral ratio of 2,5-dihydroxybenzoic acid in matrix-assisted laser desorption/ionization doi:10.1002/rcm.6534
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Frequency-Scanning MALDI Linear Ion Trap Mass Spectrometer for Large Biomolecular Ion Detection First authordoi:10.1021/ac202083c
Reaction Dynamics 2003–2008
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Dynamics of the reaction C(³P) + SiH₄: Experiments and calculations First authordoi:10.1063/1.3000005
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Exploring the dynamics of reaction N + SiH₄ with crossed molecular-beam experiments and quantum-chemical calculations First authordoi:10.1063/1.3005652
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Investigations of silicon–nitrogen hydrides from reaction of nitrogen atoms with silane: Experiments and calculations doi:10.1021/jp804435y
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Nonstatistical spin dynamics in photodissociation of H₂O at 157 nm First authordoi:10.1063/1.2830710
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Development of a stable source of atomic oxygen with a pulsed high-voltage discharge and its application to crossed-beam reactions First authordoi:10.1063/1.2772090
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Investigations of oxysilanes from the crossed-beam reaction of atomic oxygen with silane using tunable vacuum-ultraviolet ionization doi:10.1016/j.cplett.2007.07.048
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Photodissociation dynamics of HI and DI at 157 nm doi:10.1016/j.cplett.2007.10.017
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Photodissociation dynamics of ketene at 157.6 nm First authordoi:10.1063/1.2147221
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Molecular beam studies of the F atom reaction with propyne: Site specific reactivity doi:10.1063/1.1839865
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Photodissociation dynamics of 1,2-butadiene at 157 nm doi:10.1063/1.1782791
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Photodissociation dynamics of 1,3-butadiene at 157 nm doi:10.1021/jp047239c
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Product angular anisotropy in CO₂ photodissociation at 157 nm First authordoi:10.1016/j.cplett.2003.07.035